A high-rate aqueous symmetric pseudocapacitor based on highly graphitized onion-like carbon/birnessite-type manganese oxide nanohybrids

Abstract

We present a study on the pseudocapacitive properties of birnessite-type MnO₂ grafted on highly graphitized onion-like carbon (OLC/MnO₂). In a three-electrode setup, we evaluated two different substrates, namely a platinum disc and nickel foam. The OLC/MnO₂ nanohybrid exhibited a large specific capacitance (C_sp) of 295 and 323 F g⁻¹ (at 1 A g⁻¹) for the Pt disc and Ni foam, respectively. In addition, the Ni foam substrate exhibited much higher rate capability (power density) than the Pt disc. A symmetrical two-electrode device, fabricated with the Ni foam, showed a large C_sp of 254 F g⁻¹, a specific energy density of 5.6 W h kg⁻¹, and a high power density of 74.8 kW kg⁻¹. These values have been the highest for onion-based electrodes so far. The device showed excellent capacity retention when subjected to voltage-holding (floating) experiments for 50 h. In addition, the device showed a very short time constant (τ = 40 ms). This high rate handling ability of the OLC/MnO₂ nanohybrid, compared to literature reports, promises new opportunities for the development of aqueous-based pseudocapacitors.