A stable luminescent anionic porous metal–organic framework for moderate adsorption of CO2 and selective detection of nitro explosives

En-Long Zhou; Peng Huang; Chao Qin; Kui-Zhan Shao; Zhong-Min Su

doi:10.1039/C5TA00231A

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A stable luminescent anionic porous metal–organic framework for moderate adsorption of CO₂ and selective detection of nitro explosives†

En-Long Zhou,^a Peng Huang,^a Chao Qin,*^a Kui-Zhan Shao^a and Zhong-Min Su*^a

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* Corresponding authors

^a Key Lab of Polyoxometalate Science of Ministry of Education, Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, China
E-mail: zmsu@nenu.edu.cn, qinc703@nenu.edu.cn
Fax: +86-431-85684009
Tel: +86-431-85099108

Abstract

A stable luminescent anionic metal–organic framework with unprecedented topological structure was constructed, which showed a certain degree of framework stability in water and acid/base solutions. Furthermore, the compound showed moderate CO₂ adsorption and extremely selective detection of 2,4,6-trinitrophenol (TNP) in both an organic solvent and aqueous solution.

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Article information

DOI: https://doi.org/10.1039/C5TA00231A
Article type: Communication
Submitted: 12 Jan 2015
Accepted: 26 Feb 2015
First published: 02 Mar 2015

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J. Mater. Chem. A, 2015,3, 7224-7228

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A stable luminescent anionic porous metal–organic framework for moderate adsorption of CO₂ and selective detection of nitro explosives

E. Zhou, P. Huang, C. Qin, K. Shao and Z. Su, J. Mater. Chem. A, 2015, 3, 7224 DOI: 10.1039/C5TA00231A

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Journal of Materials Chemistry A