Thermal energy storage in a supramolecular assembly of [C6H11NH3]+[CF3COO]−(C6H11 = cyclohexyl)

Jiangbin Guo; Wen Tang; Binbin Wu; Haixia Zhao; Lasheng Long; Lansun Zheng

doi:10.1039/C5TA02166A

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Thermal energy storage in a supramolecular assembly of [C₆H₁₁NH₃]⁺[CF₃COO]⁻(C₆H₁₁ = cyclohexyl)†

Jiangbin Guo,^a Wen Tang,^a Binbin Wu,^a Haixia Zhao,*^a Lasheng Long*^a and Lansun Zheng^a

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* Corresponding authors

^a Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P.R. China
E-mail: lslong@xmu.edu.cn, hxzhao@xmu.edu.cn
Fax: +86-592-218-3047

Abstract

A supramolecular compound [C₆H₁₁NH₃]⁺[CF₃COO]⁻ was synthesized. Investigation on the structure of 1 at different temperatures reveals that it is the disorder of the anions that plays a key role in thermal energy storage. Studies on the thermal and physical properties of 1 indicate that utilization of the sensible heat in 1 can significantly enhance its ability to store thermal energy.

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Article information

DOI: https://doi.org/10.1039/C5TA02166A
Article type: Communication
Submitted: 25 Mar 2015
Accepted: 11 May 2015
First published: 11 May 2015

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J. Mater. Chem. A, 2015,3, 12616-12620

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Thermal energy storage in a supramolecular assembly of [C₆H₁₁NH₃]⁺[CF₃COO]⁻(C₆H₁₁ = cyclohexyl)

J. Guo, W. Tang, B. Wu, H. Zhao, L. Long and L. Zheng, J. Mater. Chem. A, 2015, 3, 12616 DOI: 10.1039/C5TA02166A

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Journal of Materials Chemistry A