Engineering nanostructured electrode materials for high performance sodium ion batteries: a case study of a 3D porous interconnected WS2/C nanocomposite

Abstract

Much attention is being paid to sodium ion batteries (SIBs) in view of the abundance of sodium sources and the cost issues. Layered transition metal dichalcogenides (such as MoS₂ and WS₂) have great potential to be used as anode materials for sodium storage owing to their high capacity. However, they still suffer from low rate capability and poor cycling stability. Compared to MoS₂, WS₂ has been scarcely studied in view of sodium storage. Here, we report, for the first time, a 3D porous interconnected WS₂/C nanocomposite prepared by an electrostatic spray deposition (ESD) technique, which is composed of nano-0D WS₂, nano-1D CNTs and nano-2D reduced graphene oxide. Such a nanocomposite shows excellent rate performance and long cycling stability, demonstrating great potential for its use as a sodium anode. Moreover, this strategy can be applied to other electrode materials for both lithium and sodium batteries.