Issue 39, 2016

Determination of fourteen UV filters in bathing water by headspace solid-phase microextraction and gas chromatography-tandem mass spectrometry

Abstract

A methodology based on solid-phase-microextraction (SPME) followed by gas chromatography-tandem mass spectrometry (GC-MS/MS) has been developed for the simultaneous analysis of 14 UV filters of different chemical nature in water. The extraction parameters (the extraction mode and temperature, the fibre coating, and the addition of salt) were optimised by means of experimental designs in order to select the best extraction conditions. The final proposed conditions were 10 mL of water sample with 35% NaCl added, extracted in the headspace mode with a polyacrylate (PA) fibre at 100 °C for 20 minutes. The SPME-GC-MS/MS method was validated in terms of linearity (R2 ≥ 0.9937), accuracy and precision, obtaining LODs in the range of 0.068–12 ng L−1. The validated methodology was then applied to the analysis of different bathing water samples including sea, river, spa, swimming pool, and aquapark water, allowing the detection of 10 of the 14 target compounds; some of them were found at concentrations up to 692 ng mL−1.

Graphical abstract: Determination of fourteen UV filters in bathing water by headspace solid-phase microextraction and gas chromatography-tandem mass spectrometry

Article information

Article type
Paper
Submitted
23 Jun 2016
Accepted
08 Aug 2016
First published
10 Aug 2016

Anal. Methods, 2016,8, 7069-7079

Determination of fourteen UV filters in bathing water by headspace solid-phase microextraction and gas chromatography-tandem mass spectrometry

M. Vila, M. Celeiro, J. P. Lamas, T. Dagnac, M. Llompart and C. Garcia-Jares, Anal. Methods, 2016, 8, 7069 DOI: 10.1039/C6AY01787H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements