A newly synthesized dipyrrinone derivative bearing an ethoxycarbonyl group at the pyrrolic-α position exhibited solvent-dependent dual-mode photochromism between T- and P-types. While this molecule underwent thermally reversible (T-type) photoresponsive reaction in chloroform, it became a thermally irreversible (P-type) system in methanol.
Y. Sakata, S. Fukushima, S. Akine and J. Setsune, Chem. Commun., 2016, 52, 1278 DOI: 10.1039/C5CC07625K
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