Issue 3, 2016
From the journal:

Chemical Communications

Fast lithium-ionic conduction in a new complex hydride–sulphide crystalline phase†

Atsushi Unemoto,*a   Hui Wu,b   Terrence J. Udovic,b   Motoaki Matsuo,c   Tamio Ikeshojiac  and  Shin-ichi Orimoac  

* Corresponding authors

a WPI–Advanced Institute for Materials Research (WPI–AIMR), Tohoku University, Sendai 980-8577, Japan
E-mail: unemoto@imr.tohoku.ac.jp

b NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899–6102, USA

c Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan

Abstract

A new crystalline phase derived from a 90LiBH4:10P2S5 mixture displays high lithium-ionic conductivity of log(σ/S cm−1) = −3.0 at 300 K. It is stable up to 473 K and has both a wide potential window of 0–5 V and favorable mechanical properties for battery assembly. Its incorporation into a bulk-type all-solid-state TiS2/InLi battery enabled repeated battery operation at 300 K.

Graphical abstract: Fast lithium-ionic conduction in a new complex hydride–sulphide crystalline phase

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC07793A
Article type
Communication
Submitted
17 Sep 2015
Accepted
21 Oct 2015
First published
06 Nov 2015

Chem. Commun., 2016,52, 564-566

Author version available

Download author version (PDF)

Permissions

Request permissions

Fast lithium-ionic conduction in a new complex hydride–sulphide crystalline phase

A. Unemoto, H. Wu, T. J. Udovic, M. Matsuo, T. Ikeshoji and S. Orimo, Chem. Commun., 2016, 52, 564 DOI: 10.1039/C5CC07793A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements