A highly regio- and stereo-selective palladium-catalyzed gem-difluoroallylation of arylboronic acids with γ,γ-difluoroallylic acetates has been described. The method allows the synthesis of a variety of gem-difluoroallylated arenes with a tosyloxy group on the C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C double bond, thus providing a good opportunity for down-stream transformations.
B. Zhang and X. Zhang, Chem. Commun., 2016, 52, 1238 DOI: 10.1039/C5CC08394J
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