Issue 7, 2016
From the journal:

Chemical Communications

Porphyrin-based mixed-valent Ag(i)/Ag(ii) and Cu(i)/Cu(ii) networks as efficient heterogeneous catalysts for the azide–alkyne “click” reaction and promising oxidation of ethylbenzene†

Wei Jiang,a   Jin Yang,*a   Ying-Ying Liua  and  Jian-Fang Ma*a  

* Corresponding authors

a Key Lab for Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China
E-mail: yangj808@nenu.edu.cn, majf247@yahoo.com

Abstract

By using a new porphyrin-based linker, two unusual mixed-valent Ag(I,II)– and Cu(I,II)–organic networks were synthesized. Most strikingly, 1 and 2 exhibit highly efficient catalytic activities for the azide–alkyne “click” reaction and oxidation of ethylbenzene.

Graphical abstract: Porphyrin-based mixed-valent Ag(i)/Ag(ii) and Cu(i)/Cu(ii) networks as efficient heterogeneous catalysts for the azide–alkyne “click” reaction and promising oxidation of ethylbenzene

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Article information

DOI
https://doi.org/10.1039/C5CC08456C
Article type
Communication
Submitted
12 Oct 2015
Accepted
23 Nov 2015
First published
30 Nov 2015

Chem. Commun., 2016,52, 1373-1376

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Porphyrin-based mixed-valent Ag(I)/Ag(II) and Cu(I)/Cu(II) networks as efficient heterogeneous catalysts for the azide–alkyne “click” reaction and promising oxidation of ethylbenzene

W. Jiang, J. Yang, Y. Liu and J. Ma, Chem. Commun., 2016, 52, 1373 DOI: 10.1039/C5CC08456C

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