The stereoselective synthesis of the phomopsin A tripeptide side chain was achieved by using methyl 2-(((benzyloxy)carbonyl)amino)-2-(diphenoxyphosphoryl)acetate as a common synthetic precursor for the synthesis of E-Δ-dehydroisoleucine and E-Δ-aspartate.
Y. Yasuno, A. Nishimura, Y. Yasukawa, Y. Karita, Y. Ohfune and T. Shinada, Chem. Commun., 2016, 52, 1478 DOI: 10.1039/C5CC08458J
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