Issue 7, 2016
From the journal:

Chemical Communications

trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids†

Chunfeng Chen,ab   Tianyu Wang,*b   Yunzhi Fua  and  Minghua Liu*bc  

* Corresponding authors

a Department of Materials Science and Chemical Engineering, Hainan University, Haikou, P. R. China

b Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: liumh@iccas.ac.cn, twang@iccas.ac.cn
Tel: +86-10-8261-5803

c Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, P. R. China

Abstract

Supramolecular polymer gels based on the co-assembly of bolaamphiphilic L-histidine(BolaHis) and dicarboxylic acids are dependent on the molar ratios, flexibility and cis–trans configuration of acid molecules. Thus, oligomerized rigid cis-maleic acid or flexible trans-cyclohexane dicarboxylic acid can form chiral supramolecular polymer gels with L-BolaHis.

Graphical abstract: trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids

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Article information

DOI
https://doi.org/10.1039/C5CC09210H
Article type
Communication
Submitted
06 Nov 2015
Accepted
23 Nov 2015
First published
23 Nov 2015

Chem. Commun., 2016,52, 1381-1384

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trans–cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids

C. Chen, T. Wang, Y. Fu and M. Liu, Chem. Commun., 2016, 52, 1381 DOI: 10.1039/C5CC09210H

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