Issue 14, 2016
From the journal:

Chemical Communications

Gold(i) operational in synergistic catalysis for the intermolecular α-addition reaction of aldehydes across allenamides†

Alberto Ballesteros, ORCID logo a   Pablo Morán-Poladuraa  and  Jose M. González*a  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo. C/ Julián Clavería 8, 33006 Oviedo, Spain
E-mail: jmgd@uniovi.es

Abstract

The intermolecular reaction of allenamides with aldehydes is reported. The designed approach relies on gold(I) and organocatalysis for activating the allenamides and the aldehydes respectively. Conditions to achieve an enantioselective version of this intermolecular reaction are defined.

Graphical abstract: Gold(i) operational in synergistic catalysis for the intermolecular α-addition reaction of aldehydes across allenamides

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Article information

DOI
https://doi.org/10.1039/C5CC09529H
Article type
Communication
Submitted
17 Nov 2015
Accepted
08 Jan 2016
First published
08 Jan 2016

Chem. Commun., 2016,52, 2905-2908

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Gold(I) operational in synergistic catalysis for the intermolecular α-addition reaction of aldehydes across allenamides

A. Ballesteros, P. Morán-Poladura and J. M. González, Chem. Commun., 2016, 52, 2905 DOI: 10.1039/C5CC09529H

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