NaHCO3-enhanced hydrogen production from water with Fe and in situ highly efficient and autocatalytic NaHCO3 reduction into formic acid

Jia Duo; Fangming Jin; Yuanqing Wang; Heng Zhong; Lingyun Lyu; Guodong Yao; Zhibao Huo

doi:10.1039/C5CC09611A

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NaHCO₃-enhanced hydrogen production from water with Fe and in situ highly efficient and autocatalytic NaHCO₃ reduction into formic acid†

Jia Duo,^a Fangming Jin,*^ab Yuanqing Wang,*^c Heng Zhong,^b Lingyun Lyu,^a Guodong Yao^a and Zhibao Huo^a

Author affiliations

* Corresponding authors

^a School of Environmental Science and Engineering, State Key Lab of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China
E-mail: fmjin@sjtu.edu.cn

^b Graduate School of Environmental Studies, Tohoku University, Aoba-ku, Sendai 980-8579, Japan

^c Biofunctional Catalyst Research Team, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan
E-mail: yqwang1984@gmail.com

Abstract

We report a highly efficient water splitting for CO₂ reduction into formic acid with a commercially available metal of Fe powder without adding any other catalyst. An excellent formic acid yield of more than 90% was attained.

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Article information

DOI: https://doi.org/10.1039/C5CC09611A
Article type: Communication
Submitted: 20 Nov 2015
Accepted: 20 Jan 2016
First published: 20 Jan 2016

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Chem. Commun., 2016,52, 3316-3319

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NaHCO₃-enhanced hydrogen production from water with Fe and in situ highly efficient and autocatalytic NaHCO₃ reduction into formic acid

J. Duo, F. Jin, Y. Wang, H. Zhong, L. Lyu, G. Yao and Z. Huo, Chem. Commun., 2016, 52, 3316 DOI: 10.1039/C5CC09611A

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