Cu3(BTC)2 is an efficient and reusable heterogeneous catalyst for the dehydrogenative coupling of silanes with alcohols. Activity data and CO adsorption suggest that Cu(II) and in situ generated Cu(I) are the active species. Other MOFs such as Fe(BTC), MIL-101(Cr) and UiO-66(Zr) are unable to promote this cross-coupling.
A. Dhakshinamoorthy, P. Concepcion and H. Garcia, Chem. Commun., 2016, 52, 2725 DOI: 10.1039/C5CC10216B
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