The synthesis of NiII and AlIII 10-azacorroles through coordination-induced cyclisation involving 1,2-migration

Hiroto Omori; Satoru Hiroto; Hiroshi Shinokubo

doi:10.1039/C5CC10247B

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The synthesis of Ni^II and Al^III 10-azacorroles through coordination-induced cyclisation involving 1,2-migration†

Hiroto Omori,^a Satoru Hiroto*^a and Hiroshi Shinokubo*^a

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* Corresponding authors

^a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya, Japan
E-mail: hshino@apchem.nagoya-u.ac.jp, hiroto@apchem.nagoya-u.ac.jp

Abstract

We have synthesized Ni^II and Al^III 10-azacorroles through coordination-induced cyclisation of nitrogen-bridged bisdipyrrins. Al^III 10-azacorrole displayed contrasting optoelectronic behaviours from Ni^II 10-azacorrole, underlining the different electronic effects of the azacorrole ligand from the porphyrin.

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Article information

DOI: https://doi.org/10.1039/C5CC10247B
Article type: Communication
Submitted: 13 Dec 2015
Accepted: 27 Jan 2016
First published: 27 Jan 2016
This article is Open Access

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Chem. Commun., 2016,52, 3540-3543

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The synthesis of Ni^II and Al^III 10-azacorroles through coordination-induced cyclisation involving 1,2-migration

H. Omori, S. Hiroto and H. Shinokubo, Chem. Commun., 2016, 52, 3540 DOI: 10.1039/C5CC10247B

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