Issue 14, 2016
From the journal:

Chemical Communications

Covalent triazine framework-supported palladium as a ligand-free catalyst for the selective double carbonylation of aryl iodides under ambient pressure of CO†

Zhifang Wang,a   Cuibo Liu,a   Yi Huang,ab   Yuchen Huab  and  Bin Zhang*ab  

* Corresponding authors

a Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, P. R. China
E-mail: bzhang@tju.edu.cn

b Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

Abstract

Carbonylation of aryl iodides with amines under atmospheric pressure of CO, catalyzed by Pd/CTFs (covalent triazine frameworks) without any specific additives, leads to the highly selective synthesis of α-ketoamides.

Graphical abstract: Covalent triazine framework-supported palladium as a ligand-free catalyst for the selective double carbonylation of aryl iodides under ambient pressure of CO

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Article information

DOI
https://doi.org/10.1039/C5CC10389D
Article type
Communication
Submitted
18 Dec 2015
Accepted
13 Jan 2016
First published
13 Jan 2016

Chem. Commun., 2016,52, 2960-2963

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Covalent triazine framework-supported palladium as a ligand-free catalyst for the selective double carbonylation of aryl iodides under ambient pressure of CO

Z. Wang, C. Liu, Y. Huang, Y. Hu and B. Zhang, Chem. Commun., 2016, 52, 2960 DOI: 10.1039/C5CC10389D

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