In this communication, we report an azine linked covalent organic framework based on a six-fold symmetric hexphenylbenzene (HEX) monomer functionalized with aldehyde groups. HEX-COF 1 has an average pore size of 1 nm, a surface area in excess of 1200 m2 gā1 and shows excellent sorption capability for carbon dioxide (20 wt%) and methane (2.3 wt%) at 273 K and 1 atm.
S. B. Alahakoon, C. M. Thompson, A. X. Nguyen, G. Occhialini, G. T. McCandless and R. A. Smaldone, Chem. Commun., 2016, 52, 2843 DOI: 10.1039/C5CC10408D
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