Control of interpenetration in a microporous metal–organic framework for significantly enhanced C2H2/CO2 separation at room temperature

Ganggang Chang; Bin Li; Hailong Wang; Tongliang Hu; Zongbi Bao; Banglin Chen

doi:10.1039/C5CC10598F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Control of interpenetration in a microporous metal–organic framework for significantly enhanced C₂H₂/CO₂ separation at room temperature†

Ganggang Chang,^ab Bin Li,*^b Hailong Wang,^b Tongliang Hu,^c Zongbi Bao*^ab and Banglin Chen*^b

Author affiliations

* Corresponding authors

^a Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
E-mail: baozb@zju.edu.cn

^b Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
E-mail: bin.li@utsa.edu, banglin.chen@utsa.edu
Fax: (+1)-210-458-7428

^c Department of Chemistry, TKL of Metal- and Molecule-Based Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Abstract

A novel non-interpenetrated three-dimensional porous metal–organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions. The resulting UTSA-68a shows a notably higher porosity and adsorption selectivity (3.5–5) for C₂H₂/CO₂ separation compared to that of doubly interpenetrated ZJU-30a (1.7–2.4) at room temperature.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C5CC10598F
Article type: Communication
Submitted: 27 Dec 2015
Accepted: 26 Jan 2016
First published: 26 Jan 2016

Download Citation

Chem. Commun., 2016,52, 3494-3496

Permissions

Request permissions

Control of interpenetration in a microporous metal–organic framework for significantly enhanced C₂H₂/CO₂ separation at room temperature

G. Chang, B. Li, H. Wang, T. Hu, Z. Bao and B. Chen, Chem. Commun., 2016, 52, 3494 DOI: 10.1039/C5CC10598F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications