Issue 26, 2016
From the journal:

Chemical Communications

Metal-center exchange of tetrahedral cages: single crystal to single crystal and spin-crossover properties†

Feng-Li Zhang,a   Jia-Qian Chen,a   Long-Fang Qin,a   Lei Tian,a   Zaijun Li,a   Xuehong Renb  and  Zhi-Guo Gu*a  

* Corresponding authors

a The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P. R. China
E-mail: zhiguogu@jiangnan.edu.cn

b The Key Laboratory of Eco-textiles of Ministry of Education, College of Textiles and Clothing, Jiangnan University, Wuxi 214122, P. R. China

Abstract

An effective single crystal to single crystal transformation from a tetrahedral Ni cage to an FeNi cage was demonstrated. The iron(II) centers of the FeNi cage can be induced to display spin crossover behaviors with an increasing amount of Fe(II) ions. The SCSC metal-center exchange provides a powerful approach to modify solid magnetic properties.

Graphical abstract: Metal-center exchange of tetrahedral cages: single crystal to single crystal and spin-crossover properties

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Article information

DOI
https://doi.org/10.1039/C6CC00711B
Article type
Communication
Submitted
25 Jan 2016
Accepted
01 Mar 2016
First published
02 Mar 2016

Chem. Commun., 2016,52, 4796-4799

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Metal-center exchange of tetrahedral cages: single crystal to single crystal and spin-crossover properties

F. Zhang, J. Chen, L. Qin, L. Tian, Z. Li, X. Ren and Z. Gu, Chem. Commun., 2016, 52, 4796 DOI: 10.1039/C6CC00711B

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