Issue 29, 2016
From the journal:

Chemical Communications

Visible-light-driven photocatalytic water oxidation catalysed by iron-based metal–organic frameworks†

Yu Horiuchi,*a   Takashi Toyao,b   Kenta Miyahara,a   Lionet Zakary,a   Dang Do Van,a   Yusuke Kamata,a   Tae-Ho Kim,c   Soo Wohn Leed  and  Masaya Matsuoka*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1, Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan
E-mail: horiuchi@chem.osakafu-u.ac.jp, matsumac@chem.osakafu-u.ac.jp
Fax: +81-72-254-9910
Tel: +81-72-254-9282

b Institute for Catalysis, Hokkaido University, N-21, W-10, Sapporo, Hokkaido, Japan

c Division of Mechanics and ICT Convergence Engineering, Sun Moon University, Republic of Korea

d Department of Environmental and Bio-Chemical Engineering, SunMoon University, GalSan-Ri, Tangjung-Myon, Asan Chung-nam 336708, Republic of Korea

Abstract

An iron-based metal–organic framework, MIL-101(Fe), promotes photocatalytic water oxidation to produce oxygen from aqueous silver nitrate solution under visible-light irradiation. The finely dispersed iron-oxo clusters embedded as nodes of the porous framework would contribute importantly to the efficient promotion of the reaction as compared to bulk hematite (α-Fe2O3).

Graphical abstract: Visible-light-driven photocatalytic water oxidation catalysed by iron-based metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C6CC00730A
Article type
Communication
Submitted
25 Jan 2016
Accepted
15 Mar 2016
First published
15 Mar 2016

Chem. Commun., 2016,52, 5190-5193

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Visible-light-driven photocatalytic water oxidation catalysed by iron-based metal–organic frameworks

Y. Horiuchi, T. Toyao, K. Miyahara, L. Zakary, D. D. Van, Y. Kamata, T. Kim, S. W. Lee and M. Matsuoka, Chem. Commun., 2016, 52, 5190 DOI: 10.1039/C6CC00730A

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