Issue 28, 2016

Syntheses and magnetic properties of a pyrimidyl-substituted nitronyl nitroxide radical and its cobalt(ii) complexes

Abstract

A new bis-bidentate nitronyl nitroxide radical with a pyrimidyl substituent group and two Co(II) complexes of this ligand were synthesized and characterized. Field-induced single-molecule magnet behavior was firstly observed in the nitronyl nitroxide radical-bridged complexes.

Graphical abstract: Syntheses and magnetic properties of a pyrimidyl-substituted nitronyl nitroxide radical and its cobalt(ii) complexes

Supplementary files

Article information

Article type
Communication
Submitted
29 Jan 2016
Accepted
09 Mar 2016
First published
17 Mar 2016

Chem. Commun., 2016,52, 5033-5036

Syntheses and magnetic properties of a pyrimidyl-substituted nitronyl nitroxide radical and its cobalt(II) complexes

J. Wang, J. Li, S. Zhang, X. Zhao, D. Shao and X. Wang, Chem. Commun., 2016, 52, 5033 DOI: 10.1039/C6CC00915H

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