Issue 23, 2016
From the journal:

Chemical Communications

Reversible transformation of self-assemblies and fluorescence by protonation–deprotonation in pyrimidinylene–phenylene macrocycles†

Duoduo Xiao,a   Siqi Zhang,b   Dengqing Zhang,a   Dahai Xie,a   Qingdao Zeng,b   Yunjie Xiang,*a   Ruguang Ning,a   Xianying Li*c  and  Wusong Jin*a  

* Corresponding authors

a State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Road, Songjiang, Shanghai 201620, P. R. China
E-mail: yjxiang@dhu.edu.cn, wsjin@dhu.edu.cn

b CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology, 11 Zhongguancun Beiyitiao, Beijing 100190, P. R. China

c School of Environmental Science and Engineering, Donghua University, 2999 North Renmin Road, Songjiang, Shanghai 201620, P. R. China
E-mail: seanlee@dhu.edu.cn

Abstract

We describe herein that the self-assembled nanoobjects based on pyrimidinylene–phenylene macrocycles, 1 and 2, which possess the capability to respond to acid-stimuli by proton binding, can undergo reversible transformation of self-assemblies and fluorescence switching by protonation–deprotonation.

Graphical abstract: Reversible transformation of self-assemblies and fluorescence by protonation–deprotonation in pyrimidinylene–phenylene macrocycles

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Article information

DOI
https://doi.org/10.1039/C6CC00943C
Article type
Communication
Submitted
30 Jan 2016
Accepted
18 Feb 2016
First published
19 Feb 2016

Chem. Commun., 2016,52, 4357-4360

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Reversible transformation of self-assemblies and fluorescence by protonation–deprotonation in pyrimidinylene–phenylene macrocycles

D. Xiao, S. Zhang, D. Zhang, D. Xie, Q. Zeng, Y. Xiang, R. Ning, X. Li and W. Jin, Chem. Commun., 2016, 52, 4357 DOI: 10.1039/C6CC00943C

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