Issue 23, 2016
From the journal:

Chemical Communications

N-Tosyl-1,5,2,6-dithiadiazocane: a waste-free electrophilic sulfur reagent for the efficient synthesis of medium-ring S,N-heterocycles†

Tomas Javorskis,a   Gintautas Bagdžiūnasb  and  Edvinas Orentas*a  

* Corresponding authors

a Department of Organic Chemistry, Vilnius University, Naugarduko 24, 03225 Vilnius, Lithuania
E-mail: edvinas.orentas@chf.vu.lt
Fax: +370-5-233-0987

b Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilėnų pl. 19, 50254 Kaunas, Lithuania

Abstract

We report on the application of an eight-membered C2-symmetric sulfenamide derivative as a new convenient and highly reactive electrophilic sulfur–nucleophilic nitrogen synthon for the concise synthesis of medium-ring S,N-heterocyclic systems.

Graphical abstract: N-Tosyl-1,5,2,6-dithiadiazocane: a waste-free electrophilic sulfur reagent for the efficient synthesis of medium-ring S,N-heterocycles

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Article information

DOI
https://doi.org/10.1039/C6CC01068G
Article type
Communication
Submitted
02 Feb 2016
Accepted
18 Feb 2016
First published
19 Feb 2016

Chem. Commun., 2016,52, 4325-4328

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N-Tosyl-1,5,2,6-dithiadiazocane: a waste-free electrophilic sulfur reagent for the efficient synthesis of medium-ring S,N-heterocycles

T. Javorskis, G. Bagdžiūnas and E. Orentas, Chem. Commun., 2016, 52, 4325 DOI: 10.1039/C6CC01068G

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