The combination of aminocatalysis with N-heterocyclic carbene catalysis has been extended to a switchable dual catalytic system, which allowed a direct enantioselective entry to bridged bicyclo[3.n.1] ring systems and the total synthesis of the natural product (1R)-suberosanone.
Y. Ren, M. Presset, J. Godemert, N. Vanthuyne, J. Naubron, M. Giorgi, J. Rodriguez and Y. Coquerel, Chem. Commun., 2016, 52, 6565 DOI: 10.1039/C6CC01689H
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