Issue 28, 2016

Bi(iii) polybromides: a new chapter in coordination chemistry of bismuth

Abstract

A new family of bismuth coordination compounds – Bi(III) polybromides – is introduced. Four representatives of this class – (N-EtPy)3[Bi2Br9](Br2)2 (1), (4-MePyH)3[Bi2Br9](Br2) (2), (H2bpe){[BiBr5]}(Br2) (3) and (BPB)2[BiBr5(Br3)](Br3)(Br2) (4) – were obtained in a simple way from HBr solutions of BiBr3 with added Br2, highlighting the diversity of the structural types in the new family of complexes.

Graphical abstract: Bi(iii) polybromides: a new chapter in coordination chemistry of bismuth

Supplementary files

Article information

Article type
Communication
Submitted
25 Feb 2016
Accepted
10 Mar 2016
First published
10 Mar 2016

Chem. Commun., 2016,52, 5061-5063

Bi(III) polybromides: a new chapter in coordination chemistry of bismuth

S. A. Adonin, I. D. Gorokh, D. G. Samsonenko, M. N. Sokolov and V. P. Fedin, Chem. Commun., 2016, 52, 5061 DOI: 10.1039/C6CC01704E

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