Issue 35, 2016
From the journal:

Chemical Communications

Formation of a unique ‘unsupported’ hydridic stannate(ii)†

María Fernández-Millán,ab   Lucy K. Allen,a   Raúl García-Rodríguez,*a   Andrew D. Bond,a   Marta E. G. Mosquera*b  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK
E-mail: dsw1000@cam.ac.uk, rg489@cam.ac.uk

b Chemistry Department, University of Alcalá, Spain
E-mail: martaeg.mosquera@uah.es

Abstract

The reaction of the amido-stannate LiSn(NMe2)3 with the phosphine–borane tBu2PHBH3 gives the SnII hydride [(Me2NH)2Li{BH3P(tBu)2}2Sn(H)]; the first example of a hydridic stannate(II) that is not supported by transition metal or ligand bonding.

Graphical abstract: Formation of a unique ‘unsupported’ hydridic stannate(ii)

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Article information

DOI
https://doi.org/10.1039/C6CC01885H
Article type
Communication
Submitted
02 Mar 2016
Accepted
04 Apr 2016
First published
04 Apr 2016

Chem. Commun., 2016,52, 5993-5996

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Formation of a unique ‘unsupported’ hydridic stannate(II)

M. Fernández-Millán, L. K. Allen, R. García-Rodríguez, A. D. Bond, M. E. G. Mosquera and D. S. Wright, Chem. Commun., 2016, 52, 5993 DOI: 10.1039/C6CC01885H

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