Issue 29, 2016

K+-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(iii) complex crystallites

Abstract

A semi-rigid ligand could capture effectively Yb3+ ions to form a stable Yb3+ complex and provide a potential cavity to accommodate alkali metal ions. Only K+ ions could induce the Yb3+ complex to form a 1D coordination polymer and promote the in situ formation of an NIR membrane coated with bigger Yb3+ complex crystallites under mild conditions.

Graphical abstract: K+-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(iii) complex crystallites

Supplementary files

Article information

Article type
Communication
Submitted
04 Mar 2016
Accepted
09 Mar 2016
First published
09 Mar 2016

Chem. Commun., 2016,52, 5124-5127

K+-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(III) complex crystallites

W. Chen, X. Tang, W. Dou, Z. Ju, B. Xu, W. Xu and W. Liu, Chem. Commun., 2016, 52, 5124 DOI: 10.1039/C6CC01938B

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