Sulfamic acid (NH3–SO3) is an acidic zwitterion with many applications. N-Alkylated derivatives are introduced, which can be used as a new class of metal extractants R2NH–SO3 and as new super-acidic ionic liquids [R2NH–SO3H][Tf2N]. The synthesis, properties and novel applications of this versatile platform are discussed.
D. Dupont, E. Renders, S. Raiguel and K. Binnemans, Chem. Commun., 2016, 52, 7032 DOI: 10.1039/C6CC02350A
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