Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2

Anis Tlili; Arnaud Voituriez; Angela Marinetti; Pierre Thuéry; Thibault Cantat

doi:10.1039/C6CC02809H

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Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO₂†

Anis Tlili,^ab Arnaud Voituriez,*^b Angela Marinetti,*^b Pierre Thuéry^a and Thibault Cantat*^a

Author affiliations

* Corresponding authors

^a NIMBE, CEA, CNRS, Université Paris-Saclay, Gif-sur-Yvette, France
E-mail: thibault.cantat@cea.fr
Web: http://iramis.cea.fr/Pisp/thibault.cantat/index.html
Fax: +33 1 6908 6640

^b Institut de Chimie des Substances Naturelles, CNRS UPR 2301, Université Paris-Sud, Université Paris-Saclay, 1 av. de la Terrasse, 91198 Gif-sur-Yvette, France
E-mail: arnaud.voituriez@cnrs.fr, angela.marinetti@cnrs.fr

Abstract

The benefit of combining both a Lewis acid and a Lewis base in a catalytic system has been established for the hydroboration of CO₂, using ferrocene-based phosphine, borane and phosphino-borane derivatives.

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Article information

DOI: https://doi.org/10.1039/C6CC02809H
Article type: Communication
Submitted: 04 Apr 2016
Accepted: 11 May 2016
First published: 11 May 2016

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Chem. Commun., 2016,52, 7553-7555

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Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO₂

A. Tlili, A. Voituriez, A. Marinetti, P. Thuéry and T. Cantat, Chem. Commun., 2016, 52, 7553 DOI: 10.1039/C6CC02809H

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