A Pt/Al2O3-supported metal–organic framework film as the size-selective core–shell hydrogenation catalyst

Sonia Aguado; Sawsan El-Jamal; Frederic Meunier; Jerome Canivet; David Farrusseng

doi:10.1039/C6CC03096C

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A Pt/Al₂O₃-supported metal–organic framework film as the size-selective core–shell hydrogenation catalyst†

Sonia Aguado,‡^a Sawsan El-Jamal,^a Frederic Meunier,^a Jerome Canivet*^a and David Farrusseng^a

Author affiliations

* Corresponding authors

^a IRCELYON, UMR CNRS 5256 – Université Lyon 1, 2 av. Albert Einstein, 69626 Villeurbanne Cedex, France
E-mail: jerome.canivet@ircelyon.univ-lyon1.fr

Abstract

The substituted imidazolate-based MOF (SIM-1) easily forms a homogeneous layer at the surface of millimetric platinum-loaded alumina beads. This new core–shell SIM-1@Pt/Al₂O₃ catalyst shows the fine molecular sieving effect for the Pt-catalyzed hydrogenation of carbon–carbon double bonds.

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Article information

DOI: https://doi.org/10.1039/C6CC03096C
Article type: Communication
Submitted: 13 Apr 2016
Accepted: 05 May 2016
First published: 05 May 2016

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Chem. Commun., 2016,52, 7161-7163

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A Pt/Al₂O₃-supported metal–organic framework film as the size-selective core–shell hydrogenation catalyst

S. Aguado, S. El-Jamal, F. Meunier, J. Canivet and D. Farrusseng, Chem. Commun., 2016, 52, 7161 DOI: 10.1039/C6CC03096C

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Chemical Communications