Issue 56, 2016
From the journal:

Chemical Communications

Ullmann coupling reaction of aryl chlorides on Au(111) using dosed Cu as a catalyst and the programmed growth of 2D covalent organic frameworks†

Ke Ji Shi,a   Xin Zhang,a   Chen Hui Shu,a   Deng Yuan Li,a   Xin Yan Wua  and  Pei Nian Liu*a  

* Corresponding authors

a Shanghai Key Laboratory of Functional Materials Chemistry, Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, China
E-mail: liupn@ecust.edu.cn
Fax: +86-21-64250552

Abstract

The efficiency of Ullmann reaction of aryl chlorides on an Au(111) surface has been substantially increased by using dosed Cu as a catalyst. The different reactivity of aryl bromides and aryl chlorides has been exploited to design a programmed, on-surface synthesis to form 2D covalent organic frameworks.

Graphical abstract: Ullmann coupling reaction of aryl chlorides on Au(111) using dosed Cu as a catalyst and the programmed growth of 2D covalent organic frameworks

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Article information

DOI
https://doi.org/10.1039/C6CC03137D
Article type
Communication
Submitted
14 Apr 2016
Accepted
13 Jun 2016
First published
13 Jun 2016

Chem. Commun., 2016,52, 8726-8729

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Ullmann coupling reaction of aryl chlorides on Au(111) using dosed Cu as a catalyst and the programmed growth of 2D covalent organic frameworks

K. J. Shi, X. Zhang, C. H. Shu, D. Y. Li, X. Y. Wu and P. N. Liu, Chem. Commun., 2016, 52, 8726 DOI: 10.1039/C6CC03137D

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