Issue 54, 2016
From the journal:

Chemical Communications

[Au25(SR)18]22−: a noble metal cluster dimer in the gas phase†

Ananya Baksi,‡a   Papri Chakraborty,‡a   Shridevi Bhat,‡a   Ganapati Natarajana  and  Thalappil Pradeep*a  

* Corresponding authors

a Department of Chemistry, DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Indian Institute of Technology Madras, Chennai 600 036, India
E-mail: pradeep@iitm.ac.in
Fax: +91-44-2257-0545

Abstract

We present the first example of dimer formation in the monolayer protected atomically precise cluster system, Au25(SR)18, using ion mobility mass spectrometry. These transient species are shown to be important in explaining chemical reactivity between clusters.

Graphical abstract: [Au25(SR)18]22−: a noble metal cluster dimer in the gas phase

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Article information

DOI
https://doi.org/10.1039/C6CC03202H
Article type
Communication
Submitted
16 Apr 2016
Accepted
06 Jun 2016
First published
06 Jun 2016

Chem. Commun., 2016,52, 8397-8400

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[Au25(SR)18]22−: a noble metal cluster dimer in the gas phase

A. Baksi, P. Chakraborty, S. Bhat, G. Natarajan and T. Pradeep, Chem. Commun., 2016, 52, 8397 DOI: 10.1039/C6CC03202H

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