Encapsulation of LnIII ions/Ag nanoparticles within Cd(II) boron imidazolate frameworks for tuning luminescence emission

Min Liu; Shumei Chen; Tian Wen; Jian Zhang

doi:10.1039/C6CC03285K

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Encapsulation of Ln^III ions/Ag nanoparticles within Cd(ii) boron imidazolate frameworks for tuning luminescence emission†

Min Liu,^ab Shumei Chen,*^ab Tian Wen

*^b and Jian Zhang^b

Author affiliations

* Corresponding authors

^a College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
E-mail: csm@fzu.edu.cn

^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: twen@fjirsm.ac.cn

Abstract

Two Cd(II) boron imidazolate frameworks (BIF-80/81) with different topologies have been synthesized by the targeted assembly of aromatic carboxylate, tetradentate imidazolate ligands, possessing tunable luminescence emission properties. Hydroxy-functional neutral BIF-80 shows an obvious blue shift of luminescence after loading Ag nanoparticles (NPs) while the first reported anionic BIF-81 in the BIF system with blue emission can tune the white-light emission via doping mixed Ln³⁺ in an appropriate ratio (Ln = Eu and Tb).

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Article information

DOI: https://doi.org/10.1039/C6CC03285K
Article type: Communication
Submitted: 19 Apr 2016
Accepted: 08 Jun 2016
First published: 08 Jun 2016

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Chem. Commun., 2016,52, 8577-8580

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Encapsulation of Ln^III ions/Ag nanoparticles within Cd(II) boron imidazolate frameworks for tuning luminescence emission

M. Liu, S. Chen, T. Wen and J. Zhang, Chem. Commun., 2016, 52, 8577 DOI: 10.1039/C6CC03285K

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