We report here how the crystallinity of AuNPs and the choice of binding sites of molecular cross-linkers control their aggregation. The combination of different binding moieties (N-oxides, ArF-I) and the reactivity of the particles' facets allow control over the organization and crystallinity of the AuNP assemblies.
M. Boterashvili, T. Shirman, R. Popovitz-Biro, Q. Wen, M. Lahav and M. E. van der Boom, Chem. Commun., 2016, 52, 8079 DOI: 10.1039/C6CC03352K
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