Issue 68, 2016

Vacuum synthesis of magnetic aluminum phthalocyanine on Au(111)

Abstract

Air-unstable magnetic aluminum phthalocyanine (AlPc) molecules are prepared by an on-surface metalation reaction of phthalocyanine with aluminum (Al) atoms on Au(111) in ultrahigh vacuum. Experiments and density functional theory calculations show that an unpaired spin is located on the conjugated isoindole lobes of the molecule rather than at the Al position.

Graphical abstract: Vacuum synthesis of magnetic aluminum phthalocyanine on Au(111)

Supplementary files

Article information

Article type
Communication
Submitted
22 Apr 2016
Accepted
03 Jul 2016
First published
05 Jul 2016

Chem. Commun., 2016,52, 10338-10341

Vacuum synthesis of magnetic aluminum phthalocyanine on Au(111)

I. Hong, N. Li, Y. Zhang, H. Wang, H. Song, M. Bai, X. Zhou, J. Li, G. Gu, X. Zhang, M. Chen, J. M. Gottfried, D. Wang, J. Lü, L. Peng, S. Hou, R. Berndt, K. Wu and Y. Wang, Chem. Commun., 2016, 52, 10338 DOI: 10.1039/C6CC03359H

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