Addition of sulfonated terminal ligands into a Ru,Rh,Ru photocatalyst has a significant impact on the excited-state properties of the complex. The hydrophilic photocatalyst demonstrates increased solubility and H2 production in aqueous solutions. H2 production is observed under aerobic conditions for the new complex, a stark contrast to the hydrophobic analog in organic solvents.
T. R. Canterbury, S. M. Arachchige, K. J. Brewer and R. B. Moore, Chem. Commun., 2016, 52, 8663 DOI: 10.1039/C6CC03370A
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