Magnesium triflate was found to effectively catalyze the tert-amino effect reaction (T-reaction) involving ethyl 3-(2-(dialkylamino)-phenyl)-2-nitroacrylates leading to tetrahydroquinoline nitroester derivatives. These compounds can be readily transformed to the corresponding valuable spirohydantoin derivatives.
J. F. Briones and G. S. Basarab, Chem. Commun., 2016, 52, 8541 DOI: 10.1039/C6CC03600G
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