Markovnikov hydrothiolation of 1,1-disubstituted and trisubstituted olefins (20 examples) is catalyzed by Lewis acids, including the air-stable trityl-cation salt [(MeOC6H4)CPh2][BF4] 3.
![Graphical abstract: The air-stable carbocation salt [(MeOC6H4)CPh2][BF4] in Lewis acid catalyzed hydrothiolation of alkenes](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C6CC03970G&imageInfo.ImageIdentifier.Year=2016)
E. Mosaferi, D. Ripsman and D. W. Stephan, Chem. Commun., 2016, 52, 8291 DOI: 10.1039/C6CC03970G
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