Gold-catalyzed [3+2]-annulations of α-aryl diazonitriles with ynamides and allenamides yield 1-amino-1H-indenes in two distinct pathways; the success of these annulations relies on the high electrophilicity of α-cyano arylgold carbenes to activate an ionic pathway.
![Graphical abstract: Gold-catalyzed [3+2]-annulations of α-aryl diazonitriles with ynamides and allenamides to yield 1-amino-1H-indenes](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C6CC04308A&imageInfo.ImageIdentifier.Year=2016)
R. R. Singh, S. K. Pawar, M. Huang and R. Liu, Chem. Commun., 2016, 52, 11434 DOI: 10.1039/C6CC04308A
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