A three-coordinate Fe(II) center within a [3Fe–(μ3-S)] cluster that provides an accessible coordination site

Yousoon Lee; Khalil A. Abboud; Ricardo García-Serres; Leslie J. Murray

doi:10.1039/C6CC04671A

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A three-coordinate Fe(ii) center within a [3Fe–(μ₃-S)] cluster that provides an accessible coordination site†

Yousoon Lee,^a Khalil A. Abboud,^a Ricardo García-Serres^b and Leslie J. Murray*^a

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* Corresponding authors

^a University of Florida, Department of Chemistry, Center for Catalysis, Gainesville, FL 32611-7200, USA
E-mail: murray@chem.ufl.edu
Tel: +1-352-392-0564

^b Univ. Grenoble Alpes, LCBM/PMB and CEA, IRTSV/CBM/PMB and CNRS, LCBM UMR 5249, PMB, 38000 Grenoble, France
E-mail: ricardo.garcia@cea.fr

Abstract

A μ₃-sulfide bridged triiron cluster(II,II,III) supported by a cyclophane ligand undergoes metal-based reduction to yield an all-ferrous species. The latter complex incorporates a three-coordinate iron center that provides an accessible coordination site to a solvent molecule.

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Article information

DOI: https://doi.org/10.1039/C6CC04671A
Article type: Communication
Submitted: 03 Jun 2016
Accepted: 27 Jun 2016
First published: 01 Jul 2016

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Chem. Commun., 2016,52, 9295-9298

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A three-coordinate Fe(II) center within a [3Fe–(μ₃-S)] cluster that provides an accessible coordination site

Y. Lee, K. A. Abboud, R. García-Serres and L. J. Murray, Chem. Commun., 2016, 52, 9295 DOI: 10.1039/C6CC04671A

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