Issue 66, 2016
From the journal:

Chemical Communications

Unexpected suppression of spin–lattice relaxation via high magnetic field in a high-spin iron(iii) complex†

Joseph M. Zadrozny,a   Michael J. Graham,a   Matthew D. Krzyaniak,ab   Michael R. Wasielewskiab  and  Danna E. Freedman*a  

* Corresponding authors

a Department of Chemistry, Northwestern University, Evanston, IL, USA
E-mail: danna.freedman@northwestern.edu

b Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, Evanston, IL, USA

Abstract

A counterintuitive three-order of magnitude slowing of the spin–lattice relaxation rate is observed in a high spin qubit at high magnetic field via multifrequency pulsed electron paramagnetic resonance measurements.

Graphical abstract: Unexpected suppression of spin–lattice relaxation via high magnetic field in a high-spin iron(iii) complex

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Article information

DOI
https://doi.org/10.1039/C6CC05094H
Article type
Communication
Submitted
17 Jun 2016
Accepted
21 Jul 2016
First published
27 Jul 2016

Chem. Commun., 2016,52, 10175-10178

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Unexpected suppression of spin–lattice relaxation via high magnetic field in a high-spin iron(III) complex

J. M. Zadrozny, M. J. Graham, M. D. Krzyaniak, M. R. Wasielewski and D. E. Freedman, Chem. Commun., 2016, 52, 10175 DOI: 10.1039/C6CC05094H

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