Issue 71, 2016
From the journal:

Chemical Communications

A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc3N@Ih-C80−)2 dimers†

Dmitri V. Konarev, ORCID logo *a   Leokadiya V. Zorina,b   Salavat S. Khasanov,b   Alexey A. Popov,c   Akihiro Otsuka,d   Hideki Yamochi,d   Gunzi Saitoef  and  Rimma N. Lyubovskayaa  

* Corresponding authors

a Institute of Problems of Chemical Physics RAS, Chernogolovka, Moscow region, 142432 Russia
E-mail: konarev3@yandex.ru

b Institute of Solid State Physics RAS, Chernogolovka, Moscow region, 142432 Russia

c Leibniz Institute for Solid State and Materials Research Helmholtzstraße 20, 01069 Dresden, Germany

d Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

e Faculty of Agriculture, Meijo University, 1-501 Shiogamaguchi, Tempaku-ku, Nagoya 468-8502, Japan

f Toyota Physical and Chemical Research Institute, 41-1, Yokomichi, Nagakute, Aichi 480-1192, Japan

Abstract

Reduction of scandium nitride clusterfullerene, Sc3N@Ih-C80, by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na+)}2(Sc3N@Ih-C80−)2·2.5C6H4Cl2 (1) salt. The Sc3N@Ih-C80˙− radical anions are dimerized to form single-bonded (Sc3N@Ih-C80−)2 dimers.

Graphical abstract: A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc3N@Ih-C80−)2 dimers

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Article information

DOI
https://doi.org/10.1039/C6CC05550H
Article type
Communication
Submitted
05 Jul 2016
Accepted
03 Aug 2016
First published
04 Aug 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 10763-10766

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A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc3N@Ih-C80−)2 dimers

D. V. Konarev, L. V. Zorina, S. S. Khasanov, A. A. Popov, A. Otsuka, H. Yamochi, G. Saito and R. N. Lyubovskaya, Chem. Commun., 2016, 52, 10763 DOI: 10.1039/C6CC05550H

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