A hexameric [MnIII18Na6] wheel based on [MnIII3O]7+ sub-units

Maria Manoli; Ross Inglis; Stergios Piligkos; Lan Yanhua; Wolfgang Wernsdorfer; Euan K. Brechin; Anastasios J. Tasiopoulos

doi:10.1039/C6CC06644E

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A hexameric [Mn ^III₁₈Na₆] wheel based on [Mn ^III₃O]⁷⁺ sub-units†

Maria Manoli,^a Ross Inglis,^b Stergios Piligkos,^c Lan Yanhua,^d Wolfgang Wernsdorfer,‡^d Euan K. Brechin*^b and Anastasios J. Tasiopoulos

*^a

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* Corresponding authors

^a Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus
E-mail: atasio@ucy.ac.cy
Fax: +357 22895451
Tel: +357 22892765

^b EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, UK
E-mail: E.Brechin@ed.ac.uk

^c Department of Chemistry, University of Copenhagen, Universitetsparken 5, Copenhagen, Denmark

^d Institut Néel, CNRS, Grenoble Cedex 9, France

Abstract

A novel hexameric [Mn^III₁₈Na₆] wheel-like aggregate consisting of [Mn^III₃O] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [Mn^III₃O] triangles, and the only one with a wheel-like metal topology.

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Article information

DOI: https://doi.org/10.1039/C6CC06644E
Article type: Communication
Submitted: 12 Aug 2016
Accepted: 23 Sep 2016
First published: 23 Sep 2016
This article is Open Access

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Chem. Commun., 2016,52, 12829-12832

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A hexameric [Mn^III₁₈Na₆] wheel based on [Mn^III₃O]⁷⁺ sub-units

M. Manoli, R. Inglis, S. Piligkos, L. Yanhua, W. Wernsdorfer, E. K. Brechin and A. J. Tasiopoulos, Chem. Commun., 2016, 52, 12829 DOI: 10.1039/C6CC06644E

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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Chemical Communications