The palladium diphosphinoboryl pincer [{(o-PPh2C6H4)2B}PdIII] 8 was prepared from the diphosphinoborane complex 6a. The boryl functionality of the pincer displayed ambiphilic properties allowing: (1) coordination of Lewis basic pyridines to the boryl site and (2) access to palladium diphosphinoborane complex derivatives.
D. Schuhknecht, F. Ritter and M. E. Tauchert, Chem. Commun., 2016, 52, 11823 DOI: 10.1039/C6CC07079E
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