Issue 95, 2016

High performance carbon molecular sieving membranes derived from pyrolysis of metal–organic framework ZIF-108 doped polyimide matrices

Abstract

Carbon molecular sieve membranes (CMSMs) were fabricated by pyrolysis of MOF-doped polyimide mixed matrix membranes. ZIF-108 (Zn(2-nitroimidazolate)2) was used as a dopant to tailor the micropores of the as-prepared CMSMs into narrow ultramicropores, providing a remarkable combination of permeability and selectivity of membranes in CO2/CH4, O2/N2 and N2/CH4 separation.

Graphical abstract: High performance carbon molecular sieving membranes derived from pyrolysis of metal–organic framework ZIF-108 doped polyimide matrices

Supplementary files

Article information

Article type
Communication
Submitted
27 Sep 2016
Accepted
01 Nov 2016
First published
01 Nov 2016

Chem. Commun., 2016,52, 13779-13782

High performance carbon molecular sieving membranes derived from pyrolysis of metal–organic framework ZIF-108 doped polyimide matrices

W. Jiao, Y. Ban, Z. Shi, X. Jiang, Y. Li and W. Yang, Chem. Commun., 2016, 52, 13779 DOI: 10.1039/C6CC07833H

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