Issue 23, 2016
From the journal:

CrystEngComm

Anion-templated 2D frameworks from hexahydroxytriphenylene†

Mahbod Morshedi,a   Anthony C. Willisa  and  Nicholas G. White*a  

* Corresponding authors

a Research School of Chemistry, The Australian National University, 137 Sullivan's Creek Road, Acton, ACT, Australia
E-mail: nicholas.white@anu.edu.au
Web: www.nwhitegroup.com

Abstract

Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H⋯anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4− was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3−).

Graphical abstract: Anion-templated 2D frameworks from hexahydroxytriphenylene

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Article information

DOI
https://doi.org/10.1039/C6CE00297H
Article type
Communication
Submitted
03 Feb 2016
Accepted
27 Mar 2016
First published
06 Apr 2016
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2016,18, 4281-4284

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Anion-templated 2D frameworks from hexahydroxytriphenylene

M. Morshedi, A. C. Willis and N. G. White, CrystEngComm, 2016, 18, 4281 DOI: 10.1039/C6CE00297H

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