Issue 41, 2016
From the journal:

CrystEngComm

From six-coordinate to eight-coordinate iron(ii) complexes with pyridyltriazolo-pyridine frameworks†

Rosa Adam,a   Rafael Ballesteros-Garrido,a   Sacramento Ferrer, ORCID logo *b   Belén Abarca,*a   Rafael Ballesteros,*a   José Antonio Realc  and  M. Carmen Muñoz*d  

* Corresponding authors

a Departament de Química Orgànica, Universitat de València, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain

b Departament de Química Inorgànica, Universitat de València, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain

c Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, C/Catedrático José Beltrán, 2, Paterna, Valencia, Spain

d Departamento de Física Aplicada, Universitat Politècnica de València, C/Camino de Vera s/n, Valencia, Spain

Abstract

A new octacoordinated Fe(II) compound, [FeII(LN4)2](BPh4)2·3CH2Cl2, as an example of the scarce FeN8 systems, has been isolated with a tetradentate triazolopyridine-based ligand from a solution containing the related hexacoordinated [FeII(LN3)2]2+ complex, with LN3 = pyridyltriazolo-pyridyl-bromopyrimidine and LN4 = bis(pyridyltriazolo-pyridine).

Graphical abstract: From six-coordinate to eight-coordinate iron(ii) complexes with pyridyltriazolo-pyridine frameworks

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Article information

DOI
https://doi.org/10.1039/C6CE01540A
Article type
Communication
Submitted
11 Jul 2016
Accepted
09 Sep 2016
First published
13 Sep 2016

CrystEngComm, 2016,18, 7950-7954

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From six-coordinate to eight-coordinate iron(II) complexes with pyridyltriazolo-pyridine frameworks

R. Adam, R. Ballesteros-Garrido, S. Ferrer, B. Abarca, R. Ballesteros, J. A. Real and M. C. Muñoz, CrystEngComm, 2016, 18, 7950 DOI: 10.1039/C6CE01540A

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