Issue 18, 2016

Ru4+ induced colossal magnetoimpedance in Ru doped perovskite manganite at room temperature

Abstract

We have demonstrated Ru4+ induced colossal magnetoimpedance (MI) at room temperature in a ∼1 Tesla magnetic field with a pulsed laser deposited La0.7Ca0.3Mn0.7Ru0.3O3 thin film. This composition showed a large negative ∼12% MI in the low frequency range (<5 MHz), a colossal positive MI > 120% in the intermediate frequency range (5 MHz to ∼13 MHz) and a negative MI in the high frequency range (∼13 MHz to 40 MHz) at room temperature. XAS data confirmed the predominant Ru valence state was 4+ in La0.7Ca0.3Mn0.7Ru0.3O3. Ru4+ induced (i) charge carrier localization and (ii) reduced hole carrier density enhances the MI in this composition, which otherwise was not significant in mixed valences Mn3+/Mn4+ containing La0.7Ca0.3MnO3 and Ru4+/Ru5+ and Mn3+/Mn4+ mixed valences containing Ru = 0.1 and Ru = 0.2 compositions in La0.7Ca0.3Mn1−xRuxO3 (0 ≤ x ≤ 0.3) thin films.

Graphical abstract: Ru4+ induced colossal magnetoimpedance in Ru doped perovskite manganite at room temperature

Supplementary files

Article information

Article type
Paper
Submitted
23 Feb 2016
Accepted
11 Apr 2016
First published
11 Apr 2016

Phys. Chem. Chem. Phys., 2016,18, 12947-12951

Ru4+ induced colossal magnetoimpedance in Ru doped perovskite manganite at room temperature

B. Singh, Phys. Chem. Chem. Phys., 2016, 18, 12947 DOI: 10.1039/C6CP01224H

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