Issue 26, 2016
From the journal:

Physical Chemistry Chemical Physics

Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy†

Liwen F. Wan,*a   Joshua Wright,b   Brian R. Perdue,c   Timothy T. Fister,d   Soojeong Kim,d   Christopher A. Apblettc  and  David Prendergasta  

* Corresponding authors

a Joint Center for Energy Storage Research (JCESR), The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, USA
E-mail: LWan@lbl.gov

b Illinois Institute of Technology, Chicago, IL 60616, USA

c Joint Center for Energy Storage Research (JCESR), Sandia National Laboratories, Albuquerque, NM 87123, USA

d Joint Center for Energy Storage Research (JCESR), Argonne National Laboratory, Lemont, IL 60439, USA

Abstract

Following previous work predicting the electronic response of the Chevrel phase Mo6S8 upon Mg insertion (Thöle et al., Phys. Chem. Chem. Phys., 2015, 17, 22548), we provide the experimental proof, evident in X-ray absorption spectroscopy, to illustrate the charge compensation mechanism of the Chevrel phase compound during Mg insertion and de-insertion processes.

Graphical abstract: Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy

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Article information

DOI
https://doi.org/10.1039/C6CP02412B
Article type
Communication
Submitted
11 Apr 2016
Accepted
10 Jun 2016
First published
10 Jun 2016

Phys. Chem. Chem. Phys., 2016,18, 17326-17329

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Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy

L. F. Wan, J. Wright, B. R. Perdue, T. T. Fister, S. Kim, C. A. Apblett and D. Prendergast, Phys. Chem. Chem. Phys., 2016, 18, 17326 DOI: 10.1039/C6CP02412B

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