Issue 3, 2016
From the journal:

Catalysis Science & Technology

Selective hydrosilylation of N-allylimines using a (3-iminophosphine)palladium precatalyst†

Hosein Tafazoliana  and  Joseph A. R. Schmidt*a  

* Corresponding authors

a Department of Chemistry & Biochemistry, School of Green Chemistry and Engineering, College of Natural Sciences and Mathematics, The University of Toledo, 2801 W. Bancroft St. MS 602, Toledo, Ohio 43606-3390, USA
E-mail: Joseph.Schmidt@utoledo.edu
Fax: +1 419 530 4033
Tel: +1 419 530 1512

Abstract

Hydrosilylation utilizing a (3-iminophosphine)palladium catalyst leads to the selective reduction of the imine unit of allylimines. Successful reduction of twenty-five different substituted aromatic and alkyl allylimines demonstrated the scope and selectivity of this catalytic system.

Graphical abstract: Selective hydrosilylation of N-allylimines using a (3-iminophosphine)palladium precatalyst

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Article information

DOI
https://doi.org/10.1039/C5CY01859E
Article type
Communication
Submitted
30 Oct 2015
Accepted
05 Jan 2016
First published
07 Jan 2016

Catal. Sci. Technol., 2016,6, 685-689

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Selective hydrosilylation of N-allylimines using a (3-iminophosphine)palladium precatalyst

H. Tafazolian and J. A. R. Schmidt, Catal. Sci. Technol., 2016, 6, 685 DOI: 10.1039/C5CY01859E

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